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It is noted that where EL for PNTz4T (either PCBMs) is regarded as 0.31eV, and for PNOz4T is 0.12eV, Which is much small compared to the widely referenced empirical threshold value of 0.3eV (ref. 28). this indicates that the driving force of the photoinduced charge separation is reduced in the PNOz4T system compared with the PNTz4T system.
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