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This is consistent with our observation that the electroluminescence of the PNOz4T/PC71BM blend system is almost the same as that of the PNOz4T neat film as mentioned before. By making the small EL=0.12eV probable by electrochemistry and the negligibly small EgECT 0eV, We can safely say that the driving force for the charge separation is quite small in the PNOz4T/PCBM system32,39.The PNOz4T cells showed EQEs surpassing 60% at the polymer max region, apart from the cells that used PC61BM with the p/n ratio of 1:1.