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We also determined which residue with the peptide (68 85) Was sulfated via ETD MS/MS possessing a LTQ Orbitrap ETD mass spectrometer (Fig. 2d). Fragmenting the peptide via ETD MS/MS constructed the sequence ions by cleaving the bonds along the backbone of the protonated peptide to yield the C and Z ion series, manufacturing (NH2CR1HCONHR2CHCONH2+H)+ to have C2 and (H2 CR3CONHCR4H COOH+H)+ to get Z2.
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