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AbstractSodium ion secondary variety (SIB) Is a low cost and huge secondary battery for next generation large scale energy storage. The diffusion technique of large Na+ (Ionic distance is 1.12 ), about the other hand, Is viewed as slower than that of small Li+ (0.76 ). This would be a serious problem with SIB as compared with the Lithium ion secondary battery (LIB). thru the electrochemical impedance spectroscopy (EIS), We encouraged the diffusion constant (ve had) Of Na+ in thin films of O3 and P2 type NaCoO2 with layered fabrications. We found that our D values ( 0.5 1.5 1010cm2/s) Of Na+ are over those (11cm2/s) Of Li+ in split LiCoO2. unique, The D values of O3 NaCoO2 are even greater than those of P2 NaCoO2, Probably because O3 NaCoO2 shows successive structural phase transitions from the O3, O’3, P’3, To P3 phases with Na+ deintercalation. We further found that the service energy (impotence problems 0.4eV) For the Na+ diffusion is very much low in these layered cobalt oxides. but nevertheless, The Na+ diffusion is really reliant on the crystal structure. for example, most of the Na+ diffusion in P2 Na0.66Li0.22Ti0.78O2 with split structure12 and Na3V2(PO4)313 due to NASICON (Na very Ionic CONductor) Structure are enormously fast, even though it is much slower in Li4Ti5O1214,15 with spinel framework. in a position to precisely determine the Na+ diffusion constant (def), We fabricated thin films of history of pro football salaries O3 and P2 type NaCoO2 on an Au collector electrode as a direct result the pulsed laser deposition (PLD) application. We found which the D values ( 0.5 1.5 1010cm2/s) Of Na+ are as compared to those (1 1011cm2/s16) Of Li+ in split LiCoO2.
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